|
|
propane + O2 + NADH + H+ <=> 2-propanol + NAD+ + H2O
|
1.14.13.227
propane 2-monooxygenase
|
–
|
| |
BRENDA:
BR51742
KEGG:
R10702
MetaCyc:
RXN-17568
|
|
|
|
enzyme_N6-(dihydrolipoyl)lysine + NAD+ <=> [dihydrolipoyllysine-residue(2-methylpropanoyl)transferase]-lipoyllysine + NADH + H+
|
1.8.1.4
dihydrolipoyl dehydrogenase
|
–
|
| |
BRENDA:
BR36970
KEGG:
R03815;
R07618;
R08550
MetaCyc:
1.8.1.4-RXN;
RXN-7716
SABIO-RK:
9140
|
|
|
|
succinate + CoA + ATP <=> succinyl-CoA + ADP + phosphate
|
6.2.1.13
acetate---CoA ligase (ADP-forming)
6.2.1.4
succinate---CoA ligase (GDP-forming)
6.2.1.5
succinate---CoA ligase (ADP-forming)
|
–
–
–
|
| |
BRENDA:
BR88
KEGG:
R00405
MetaCyc:
SUCCCOASYN-RXN
SABIO-RK:
260
|
|
|
|
acetyl-CoA + acetoacetate <=> acetate + acetoacetyl-CoA
|
2.8.3.1
propionate CoA-transferase
2.8.3.18
succinyl-CoA:acetate CoA-transferase
2.8.3.8
acetate CoA-transferase
2.8.3.9
butyrate---acetoacetate CoA-transferase
|
–
–
–
–
|
| |
BRENDA:
BS358821
KEGG:
R01359
MetaCyc:
ACETOACETYL-COA-TRANSFER-RXN
SABIO-RK:
1563
|
|
|
|
propionyl-CoA + NADP+ <=> acryloyl-CoA + NADPH + H+
|
1.3.1
1.3.1.84
acrylyl-CoA reductase (NADPH)
1.3.1.95
acrylyl-CoA reductase (NADH)
|
–
–
–
|
| |
BRENDA:
BR49115
KEGG:
R00919
MetaCyc:
RXN-9087
SABIO-RK:
1239
|
|
|
|
propionate + CoA + ATP <=> propionyl-CoA + ADP + phosphate
|
6.2.1.13
acetate---CoA ligase (ADP-forming)
6.2.1.5
succinate---CoA ligase (ADP-forming)
6.2.1.B11
|
–
–
–
|
| |
BRENDA:
BS163
KEGG:
R00920
MetaCyc:
PROPANOATECOA-LIGASE-RXN
|
|
|
|
3-hydroxypropionate + NAD+ <=> malonate_semialdehyde + NADH + H+
|
1.1.1.298
3-hydroxypropionate dehydrogenase (NADP+)
1.1.1.31
3-hydroxyisobutyrate dehydrogenase
1.1.1.59
3-hydroxypropionate dehydrogenase
1.1.1.60
2-hydroxy-3-oxopropionate reductase
|
–
–
–
–
|
| |
BRENDA:
BR29322
KEGG:
R01608
MetaCyc:
3-HYDROXYPROPIONATE-DEHYDROGENASE-RXN
SABIO-RK:
1753
|
|
|
|
acetyl-CoA + propionate <=> acetate + propionyl-CoA
|
2.8.3.1
propionate CoA-transferase
2.8.3.12
glutaconate CoA-transferase
2.8.3.14
5-hydroxypentanoate CoA-transferase
2.8.3.18
succinyl-CoA:acetate CoA-transferase
|
–
–
–
–
|
| |
BRENDA:
BR48124
KEGG:
R00928
MetaCyc:
PROPIONATE-COA-TRANSFERASE-RXN
SABIO-RK:
170
|
|
|
|
(R)-2-methylmalonyl-CoA <=> succinyl-CoA
|
5.4.99.2
methylmalonyl-CoA mutase
5.4.99.63
ethylmalonyl-CoA mutase
5.4.99.64
2-hydroxyisobutanoyl-CoA mutase
|
–
–
–
|
| |
BRENDA:
BR249;
BS380077;
BS390473
KEGG:
R00833
MetaCyc:
METHYLMALONYL-COA-MUT-RXN
SABIO-RK:
10453;
1174
|
|
|
|
bithionol + H2O <=> H+ + 3-hydroxypropionate + CoA
|
3.1.2.4
3-hydroxyisobutyryl-CoA hydrolase
|
–
|
| |
BRENDA:
BS446056
KEGG:
R03158
MetaCyc:
RXN-6384
SABIO-RK:
2990
|
|
|
|
2-oxobutyrate + NADH + H+ <=> DL-2-hydroxybutyrate + NAD+
|
1.1.1.1
alcohol dehydrogenase
1.1.1.110
aromatic 2-oxoacid reductase
1.1.1.27
L-lactate dehydrogenase
1.1.1.28
D-lactate dehydrogenase
1.1.1.337
L-2-hydroxycarboxylate dehydrogenase (NAD+)
1.1.1.345
D-2-hydroxyacid dehydrogenase (NAD+)
1.1.1.37
malate dehydrogenase
1.1.99.2
L-2-hydroxyglutarate dehydrogenase
|
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BS187843-a
KEGG:
R01000
|
|
|
|
bithionol + NADP+ <=> 3-oxopropanoyl-CoA + NADPH + H+
|
1.1.1
|
–
|
| |
KEGG:
R04919
|
|
|
|
propionaldehyde + CoA + NAD+ <=> propionyl-CoA + NADH + H+
|
1.2.1.10
acetaldehyde dehydrogenase (acetylating)
1.2.1.27
methylmalonate-semialdehyde dehydrogenase (CoA-acylating)
1.2.1.57
butanal dehydrogenase
1.2.1.87
propanal dehydrogenase (CoA-propanoylating)
|
–
–
–
–
|
| |
BRENDA:
BR50602
KEGG:
R09097
MetaCyc:
RXN-12736
SABIO-RK:
10853
|
|
|
|
methyl_acetate + H2O <=> acetate + methanol + H+
|
3.1.1.1
carboxylesterase
3.1.1.113
ethyl acetate hydrolase
3.1.1.114
methyl acetate hydrolase
3.1.1.3
triacylglycerol lipase
3.1.1.43
alpha-amino-acid esterase
3.1.1.6
acetylesterase
3.1.1.74
cutinase
|
–
–
–
–
–
–
–
|
| |
BRENDA:
BR52934
KEGG:
R10705
MetaCyc:
RXN-17572
|
|
|
|
malonate_semialdehyde <=> propynoate + H2O
|
4.2.1.27
acetylenecarboxylate hydratase
|
–
|
| |
BRENDA:
BR48002
KEGG:
R01611
MetaCyc:
MALONATE-SEMIALDEHYDE-DEHYDRATASE-RXN
|
|
|
|
H+ + methylglyoxal + NADH <=> Hydroxyacetone + NAD+
|
1.1.1
1.1.1.1
alcohol dehydrogenase
1.1.1.21
aldose reductase
1.1.1.75
(R)-aminopropanol dehydrogenase
|
–
–
–
–
|
| |
BRENDA:
BS188635
KEGG:
R10718
MetaCyc:
RXN0-5213
SABIO-RK:
9806
|
|
|
|
propionyl-CoA + enzyme_N6-(dihydrolipoyl)lysine <=> CoA + Enzyme_N6-(S-propyldihydrolipoyl)lysine
|
2.3.1.168
dihydrolipoyllysine-residue (2-methylpropanoyl)transferase
|
–
|
| |
KEGG:
R10998
|
|
|
|
L-2-methyl-3-oxopropionate + CoA + NAD+ <=> propionyl-CoA + CO2 + NADH + H+
|
1.2.1.27
methylmalonate-semialdehyde dehydrogenase (CoA-acylating)
|
–
|
| |
KEGG:
R00935
SABIO-RK:
1253
|
|
|
|
2-propanol + NADP+ <=> acetone + NADPH + H+
|
1.1.1.1
alcohol dehydrogenase
1.1.1.156
glycerol 2-dehydrogenase (NADP+)
1.1.1.184
carbonyl reductase (NADPH)
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.4
(R,R)-butanediol dehydrogenase
1.1.1.71
alcohol dehydrogenase [NAD(P)+]
1.1.1.80
isopropanol dehydrogenase (NADP+)
1.1.1.B4
|
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR29340
KEGG:
R01550
MetaCyc:
ISOPROPANOL-DEHYDROGENASE-NADP+-RXN
SABIO-RK:
1709
|
|
|
|
2-oxobutyrate + CoA <=> propionyl-CoA + formate
|
2.3.1
2.3.1.54
formate C-acetyltransferase
|
–
–
|
| |
BRENDA:
BS321064
KEGG:
R06987
MetaCyc:
KETOBUTFORMLY-RXN
|
|
|
|
propionyl-CoA + succinate <=> propionate + succinyl-CoA
|
2.8.3
2.8.3.1
propionate CoA-transferase
2.8.3.18
succinyl-CoA:acetate CoA-transferase
2.8.3.M4
|
–
–
–
–
|
| |
BRENDA:
BS428954
KEGG:
R11773
MetaCyc:
RXN0-268
SABIO-RK:
14385
|
|
|
|
L-2-methyl-3-oxopropionate + CoA + NAD+ <=> (R)-2-methylmalonyl-CoA + NADH + H+
|
1.2.1
|
–
|
| |
KEGG:
R03381
|
|
|
|
propionyl-AMP + CoA <=> AMP + propionyl-CoA
|
6.2.1.1
acetate---CoA ligase
6.2.1.17
propionate---CoA ligase
|
–
–
|
| |
BRENDA:
BS453711
KEGG:
R00926
|
|
|
|
1-propanol + NAD+ <=> propionaldehyde + NADH + H+
|
1.1.1.1
alcohol dehydrogenase
1.1.1.165
2-alkyn-1-ol dehydrogenase
1.1.1.192
long-chain-alcohol dehydrogenase
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.202
1,3-propanediol dehydrogenase
1.1.1.21
aldose reductase
1.1.1.244
methanol dehydrogenase
1.1.1.245
cyclohexanol dehydrogenase
1.1.1.265
3-methylbutanal reductase
1.1.1.306
S-(hydroxymethyl)mycothiol dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
1.1.1.51
3(or 17)beta-hydroxysteroid dehydrogenase
1.1.1.6
glycerol dehydrogenase
1.1.1.71
alcohol dehydrogenase [NAD(P)+]
1.1.1.73
octanol dehydrogenase
1.1.1.77
lactaldehyde reductase
1.1.1.B4
1.2.1.3
aldehyde dehydrogenase (NAD+)
|
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BS165069-a
KEGG:
R02377
MetaCyc:
RXN-13198
SABIO-RK:
2321
|
|
|
|
(S)-methylmalonyl-CoA + H+ <=> CO2 + propionyl-CoA
|
2.3.1.226
carboxymethylproline synthase
4.1.1
4.1.1.9
malonyl-CoA decarboxylase
4.1.1.94
ethylmalonyl-CoA decarboxylase
4.1.1.M5
6.4.1.3
propionyl-CoA carboxylase
|
–
–
–
–
–
–
|
| |
BRENDA:
BS1620;
BS410118
KEGG:
R00923;
R05373
MetaCyc:
METHYLMALONYL-COA-DECARBOXYLASE-RXN;
RXN0-310
SABIO-RK:
4979
|
|
|
|
acetone + O2 + NADPH + H+ <=> methyl_acetate + NADP+ + H2O
|
1.14.13.226
acetone monooxygenase (methyl acetate-forming)
|
–
|
| |
BRENDA:
BR51741
KEGG:
R10704
MetaCyc:
RXN-17567
|
|
|
|
1,2-propanediol <=> propionaldehyde + H2O
|
4.2.1.28
propanediol dehydratase
4.2.1.30
glycerol dehydratase
|
–
–
|
| |
BRENDA:
BR409
KEGG:
R02376
|
|
|
|
malonate_semialdehyde + CoA + NADP+ <=> acetyl-CoA + CO2 + NADPH
|
1.2.1
1.2.1.18
malonate-semialdehyde dehydrogenase (acetylating)
|
–
–
|
| |
BRENDA:
BR29389
KEGG:
R00706
MetaCyc:
1.2.1.18-RXN;
RXN-9958
|
|
|
|
propionyl-CoA + L-lactate <=> propionate + lactoyl-CoA
|
2.8.3.1
propionate CoA-transferase
|
–
|
| |
KEGG:
R01449
MetaCyc:
PROPIONLACT-RXN
|
|
|
|
Hydroxyacetone + NADH + H+ <=> 1,2-propanediol + NAD+
|
1.1.1.1
alcohol dehydrogenase
1.1.1.165
2-alkyn-1-ol dehydrogenase
1.1.1.4
(R,R)-butanediol dehydrogenase
1.1.1.6
glycerol dehydrogenase
|
–
–
–
–
|
| |
BRENDA:
BS165099
KEGG:
R10717
|
|
|
|
ATP + propionyl-CoA + HCO3- <=> H+ + (S)-methylmalonyl-CoA + phosphate + ADP
|
6.4.1.2
acetyl-CoA carboxylase
6.4.1.3
propionyl-CoA carboxylase
|
–
–
|
| |
BRENDA:
BR155
KEGG:
R01859
MetaCyc:
PROPIONYL-COA-CARBOXY-RXN
SABIO-RK:
1929
|
|
|
|
(2S,3S)-methylcitrate <=> H2O + 2-methyl-trans-aconitate
|
4.2.1.117
2-methylcitrate dehydratase (2-methyl-trans-aconitate forming)
4.2.1.79
2-methylcitrate dehydratase
|
–
–
|
| |
BRENDA:
BR49126
KEGG:
R11263
MetaCyc:
RXN-8979
|
|
|
|
H2O + (S)-methylmalonyl-CoA <=> H+ + CoA + methylmalonate
|
3.1.2.17
(S)-methylmalonyl-CoA hydrolase
3.1.2.20
acyl-CoA hydrolase
3.1.2.4
3-hydroxyisobutyryl-CoA hydrolase
|
–
–
–
|
| |
BRENDA:
BR47932;
BS401387
KEGG:
R02764
MetaCyc:
S-METHYLMALONYL-COA-HYDROLASE-RXN
SABIO-RK:
11293;
2641
|
|
|
|
bithionol <=> acryloyl-CoA + H2O
|
4.2.1
4.2.1.116
3-hydroxypropionyl-CoA dehydratase
4.2.1.17
enoyl-CoA hydratase
|
–
–
–
|
| |
BRENDA:
BR49125
KEGG:
R03045
MetaCyc:
RXN-6383
SABIO-RK:
2892
|
|
|
|
acetoacetate + H+ <=> acetone + CO2
|
1.8.1.5
2-oxopropyl-CoM reductase (carboxylating)
4.1.1.4
acetoacetate decarboxylase
|
–
–
|
| |
BRENDA:
BR299
KEGG:
R01366
MetaCyc:
ACETOACETATE-DECARBOXYLASE-RXN
SABIO-RK:
1568
|
|
|
|
2-(alpha-Hydroxypropyl)thiamine_diphosphate + Enzyme_N6-(lipoyl)lysine <=> Enzyme_N6-(S-propyldihydrolipoyl)lysine + thiamine_diphosphate
|
1.2.4.4
3-methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)
|
–
|
| |
KEGG:
R10997
|
|
|
|
(2S,3S)-methylcitrate <=> (Z)-2-methylaconitate + H2O
|
4.2.1.117
2-methylcitrate dehydratase (2-methyl-trans-aconitate forming)
4.2.1.79
2-methylcitrate dehydratase
|
–
–
|
| |
BRENDA:
BR456;
BS2113;
BS444085
KEGG:
R04424
MetaCyc:
2-METHYLCITRATE-DEHYDRATASE-RXN
SABIO-RK:
4111
|
|
|
|
beta-Alanine + 2-oxoglutarate <=> malonate_semialdehyde + L-glutamate
|
2.6.1.19
4-aminobutyrate---2-oxoglutarate transaminase
2.6.1.2
alanine transaminase
2.6.1.22
(S)-3-amino-2-methylpropionate transaminase
2.6.1.55
taurine---2-oxoglutarate transaminase
2.6.1.ak
|
–
–
–
–
–
|
| |
BRENDA:
BS353590
KEGG:
R00908
MetaCyc:
RXN-2901
SABIO-RK:
1228
|
|
|
|
ATP + propionate <=> diphosphate + propionyl-AMP
|
6.2.1.1
acetate---CoA ligase
6.2.1.17
propionate---CoA ligase
|
–
–
|
| |
KEGG:
R01354
|
|
|
|
lactoyl-CoA <=> acryloyl-CoA + H2O
|
4.2.1
4.2.1.54
lactoyl-CoA dehydratase
|
–
–
|
| |
BRENDA:
BS18742
KEGG:
R02963
MetaCyc:
RXN-781
|
|
|
|
malonate_semialdehyde + CoA + NADP+ <=> malonyl-CoA + NADPH + H+
|
1.2.1.18
malonate-semialdehyde dehydrogenase (acetylating)
1.2.1.75
malonyl-CoA reductase (malonate semialdehyde-forming)
|
–
–
|
| |
BRENDA:
BR49113
KEGG:
R00740
MetaCyc:
RXN-8963
|
|
|
|
Hydroxyacetone + NADP+ <=> H+ + methylglyoxal + NADPH
|
1.1.1
1.1.1.1
alcohol dehydrogenase
1.1.1.153
sepiapterin reductase (L-erythro-7,8-dihydrobiopterin forming)
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.21
aldose reductase
1.1.1.72
glycerol dehydrogenase (NADP+)
1.3.1.20
trans-1,2-dihydrobenzene-1,2-diol dehydrogenase
|
–
–
–
–
–
–
–
|
| |
BRENDA:
BS188596
KEGG:
R02528
MetaCyc:
RXN0-4281
SABIO-RK:
2450
|
|
|
|
succinate + GTP + CoA <=> succinyl-CoA + GDP + phosphate
|
6.2.1.4
succinate---CoA ligase (GDP-forming)
|
–
|
| |
BRENDA:
BR87
KEGG:
R00432
MetaCyc:
SUCCINATE--COA-LIGASE-GDP-FORMING-RXN
SABIO-RK:
259
|
|
|
|
ATP + acetyl-CoA + HCO3- <=> ADP + phosphate + malonyl-CoA + H+
|
6.4.1.2
acetyl-CoA carboxylase
6.4.1.3
propionyl-CoA carboxylase
6.4.1.4
methylcrotonoyl-CoA carboxylase
|
–
–
–
|
| |
BRENDA:
BR6444
KEGG:
R00742
MetaCyc:
ACETYL-COA-CARBOXYLTRANSFER-RXN
SABIO-RK:
542
|
|
|
|
2-oxobutyrate + thiamine_diphosphate <=> 2-(alpha-Hydroxypropyl)thiamine_diphosphate + CO2
|
1.2.4.4
3-methyl-2-oxobutanoate dehydrogenase (2-methylpropanoyl-transferring)
|
–
|
| |
KEGG:
R10996
|
|
|
|
2-oxobutyrate + phosphate + O2 <=> propanoyl_phosphate + CO2 + H2O2
|
1.2.3
|
–
|
| |
KEGG:
R00993
|
|
|
|
acetyl-CoA + oxaloacetate <=> malonyl-CoA + pyruvate
|
2.1.3.1
methylmalonyl-CoA carboxytransferase
|
–
|
| |
BRENDA:
BS320094
KEGG:
R00353
|
|
|
|
flavin + propionyl-CoA <=> reduced_flavodoxin + acryloyl-CoA
|
1.3.8.1
short-chain acyl-CoA dehydrogenase
|
–
|
| |
KEGG:
R04432
|
|
|
|
methylmalonate <=> L-2-methyl-3-oxopropionate
|
not assigned
|
–
|
| |
KEGG:
R03872
|
|
|
|
acetyl-CoA <=> acetoacetyl-CoA + CoA
|
1.1.1.34
hydroxymethylglutaryl-CoA reductase (NADPH)
2.3.1.155
acetyl-CoA C-myristoyltransferase
2.3.1.16
acetyl-CoA C-acyltransferase
2.3.1.38
[acyl-carrier-protein] S-acetyltransferase
2.3.1.9
acetyl-CoA C-acetyltransferase
|
–
–
–
–
–
|
| |
BRENDA:
BR44092
KEGG:
R00238
MetaCyc:
ACETYL-COA-ACETYLTRANSFER-RXN
SABIO-RK:
531
|
|
|
|
beta-Alanine <=> beta-alanyl-CoA
|
2.8.3
|
–
|
| |
KEGG:
R00914
|
|
|
|
propionyl-CoA + NAD+ <=> acryloyl-CoA + NADH + H+
|
1.3.1.84
acrylyl-CoA reductase (NADPH)
1.3.1.95
acrylyl-CoA reductase (NADH)
|
–
–
|
| |
BRENDA:
BR50238
KEGG:
R10161
MetaCyc:
RXN-8568
SABIO-RK:
14467
|
|
|
|
H+ + malonyl-CoA <=> CO2 + acetyl-CoA
|
2.3.1.226
carboxymethylproline synthase
2.3.1.74
chalcone synthase
4.1.1.87
malonyl-S-ACP decarboxylase
4.1.1.9
malonyl-CoA decarboxylase
|
–
–
–
–
|
| |
BRENDA:
BR340
KEGG:
R00233
MetaCyc:
MALONYL-COA-DECARBOXYLASE-RXN
SABIO-RK:
750
|
|
|
|
pyruvate + (S)-methylmalonyl-CoA <=> oxaloacetate + propionyl-CoA
|
2.1.3.1
methylmalonyl-CoA carboxytransferase
|
–
|
| |
BRENDA:
BR43948
KEGG:
R00930
MetaCyc:
2.1.3.1-RXN
|
|
|
|
propionyl-CoA + O2 <=> acryloyl-CoA + H2O2
|
1.3.3.6
acyl-CoA oxidase
|
–
|
| |
KEGG:
R12356
MetaCyc:
RXN-15977
|
|
|
|
L-lactaldehyde + NADP+ <=> methylglyoxal + NADPH + H+
|
1.1.1.156
glycerol 2-dehydrogenase (NADP+)
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.21
aldose reductase
1.1.1.283
methylglyoxal reductase (NADPH)
1.1.1.71
alcohol dehydrogenase [NAD(P)+]
1.1.1.72
glycerol dehydrogenase (NADP+)
1.1.1.78
methylglyoxal reductase (NADH)
1.2.1.49
2-oxoaldehyde dehydrogenase (NADP+)
|
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BR48480;
BS139557
KEGG:
R02260
MetaCyc:
1.1.1.283-RXN
SABIO-RK:
550;
9214
|
|
|
|
malonate_semialdehyde + CoA + NAD+ <=> acetyl-CoA + CO2 + NADH
|
1.2.1.18
malonate-semialdehyde dehydrogenase (acetylating)
1.2.1.27
methylmalonate-semialdehyde dehydrogenase (CoA-acylating)
|
–
–
|
| |
BRENDA:
BR29389-a
KEGG:
R00705
MetaCyc:
RXN-2902;
RXN-9958_WOP
SABIO-RK:
1081
|
|
|
|
(R)-2-methylmalonyl-CoA <=> (S)-methylmalonyl-CoA
|
5.1.99.1
methylmalonyl-CoA epimerase
|
–
|
| |
BRENDA:
BR204;
BS970
KEGG:
R02765
MetaCyc:
METHYLMALONYL-COA-EPIM-RXN
SABIO-RK:
2642
|
|
|
|
2-oxobutyrate + oxidized_ferredoxin + CoA <=> propionyl-CoA + reduced_ferredoxin_[iron-sulfur]_cluster + CO2 + H+
|
1.2.7.1
pyruvate synthase
1.2.7.11
2-oxoacid oxidoreductase (ferredoxin)
1.2.7.7
3-methyl-2-oxobutanoate dehydrogenase (ferredoxin)
|
–
–
–
|
| |
BRENDA:
BS189350
KEGG:
R01199
MetaCyc:
2-OXOBUTYRATE-SYNTHASE-RXN
|
|
|
|
2-propanol + NAD+ <=> acetone + NADH + H+
|
1.1.1
1.1.1.1
alcohol dehydrogenase
1.1.1.184
carbonyl reductase (NADPH)
1.1.1.2
alcohol dehydrogenase (NADP+)
1.1.1.244
methanol dehydrogenase
1.1.1.245
cyclohexanol dehydrogenase
1.1.1.268
2-(R)-hydroxypropyl-CoM dehydrogenase
1.1.1.269
2-(S)-hydroxypropyl-CoM dehydrogenase
1.1.1.35
3-hydroxyacyl-CoA dehydrogenase
1.1.1.4
(R,R)-butanediol dehydrogenase
1.1.1.406
galactitol 2-dehydrogenase (L-tagatose-forming)
1.1.1.6
glycerol dehydrogenase
1.1.1.71
alcohol dehydrogenase [NAD(P)+]
1.1.1.73
octanol dehydrogenase
1.1.1.76
(S,S)-butanediol dehydrogenase
1.1.1.80
isopropanol dehydrogenase (NADP+)
1.1.1.B4
1.1.1.M22
|
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
–
|
| |
BRENDA:
BS186841
KEGG:
R10703
MetaCyc:
RXN-17571
SABIO-RK:
7922
|
|
|
|
propionyl-CoA + phosphate <=> propanoyl_phosphate + CoA
|
2.3.1.19
phosphate butyryltransferase
2.3.1.222
phosphate propanoyltransferase
2.3.1.8
phosphate acetyltransferase
|
–
–
–
|
| |
BRENDA:
BR50416
KEGG:
R00921
MetaCyc:
PTAALT-RXN
|
|
|
|
propionate + ATP <=> propanoyl_phosphate + ADP
|
2.7.2.1
acetate kinase
2.7.2.14
branched-chain-fatty-acid kinase
2.7.2.15
propionate kinase
2.7.2.6
formate kinase
2.7.2.7
butyrate kinase
|
–
–
–
–
–
|
| |
BRENDA:
BR48584
KEGG:
R01353
MetaCyc:
PROPKIN-RXN
SABIO-RK:
1558
|
|
|
|
beta-alanyl-CoA <=> NH3 + acryloyl-CoA
|
4.3.1.6
beta-alanyl-CoA ammonia-lyase
|
–
|
| |
BRENDA:
BR3428
KEGG:
R03046
MetaCyc:
BETA-ALANYL-COA-AMMONIA-LYASE-RXN
|
|
|
|
2-methyl-trans-aconitate <=> (Z)-2-methylaconitate
|
5.3.3
|
–
|
| |
KEGG:
R11264
MetaCyc:
RXN-8977
|
|
|
|
(2S,3R)-3-hydroxybutane-1,2,3-tricarboxylate <=> succinate + pyruvate
|
4.1.3.1
isocitrate lyase
4.1.3.30
methylisocitrate lyase
|
–
–
|
| |
BRENDA:
BR390;
BS417300
KEGG:
R00409
MetaCyc:
METHYLISOCITRATE-LYASE-RXN
SABIO-RK:
866
|
|
|
|
1,2-propanediol + NAD+ <=> L-lactaldehyde + NADH + H+
|
1.1.1.77
lactaldehyde reductase
|
–
|
| |
KEGG:
R02257
|
|
|
|
dihydroxyacetone_phosphate <=> methylglyoxal + phosphate
|
4.1.2.17
L-fuculose-phosphate aldolase
4.2.3.3
methylglyoxal synthase
5.3.1.1
triose-phosphate isomerase
|
–
–
–
|
| |
BRENDA:
BR16092
KEGG:
R01016
MetaCyc:
METHGLYSYN-RXN
SABIO-RK:
176
|
|
|
|
(2S,3R)-3-hydroxybutane-1,2,3-tricarboxylate <=> (Z)-2-methylaconitate + H2O
|
4.2.1.3
aconitate hydratase
4.2.1.99
2-methylisocitrate dehydratase
|
–
–
|
| |
BRENDA:
BR471;
BS18710;
BS368299
KEGG:
R04425
MetaCyc:
4.2.1.99-RXN
SABIO-RK:
4112
|
|
|
|
propionyl-CoA + H2O + oxaloacetate <=> (2S,3S)-methylcitrate + CoA + H+
|
2.3.3.16
citrate synthase (unknown stereospecificity)
2.3.3.5
2-methylcitrate synthase
|
–
–
|
| |
BRENDA:
BR44127;
BS321797;
BS407305
KEGG:
R00931
MetaCyc:
2-METHYLCITRATE-SYNTHASE-RXN
SABIO-RK:
1249
|
|
|
|
L-lactaldehyde + NAD+ <=> methylglyoxal + NADH + H+
|
1.1.1.6
glycerol dehydrogenase
|
–
|
| |
KEGG:
R10715
|
|
|
|
malonate_semialdehyde + L-alanine <=> beta-Alanine + pyruvate
|
2.6.1.113
putrescine---pyruvate transaminase
2.6.1.18
beta-alanine---pyruvate transaminase
2.6.1.2
alanine transaminase
2.6.1.40
(R)-3-amino-2-methylpropionate---pyruvate transaminase
2.6.1.77
taurine---pyruvate aminotransferase
|
–
–
–
–
–
|
| |
BRENDA:
BR47385
KEGG:
R00907
MetaCyc:
2.6.1.18-RXN
|
|
|
|
malonyl-CoA + NADPH + H+ <=> 3-oxopropanoyl-CoA + NADP+ + H2O
|
not assigned
|
–
|
| |
KEGG:
R00744
|
|
